ROBERTO SALOMONE GettyImages
Gonzalo Higuain missed a 38th-minute penalty, won by Dybala, but soon made amends by setting up Dybala's second shortly after the break.
Juventus is now atop the standings, with 71 points, ahead of Napoli who drew Inter Milan 0-0, while Udinese is in 11th place, with 33 points.
They had matched Juve stride for stride for 10 consecutive matches up to the postponement of Juve's game against Atalanta, when Napoli were able to increase their advantage to four points.
The club were playing their first game since Astori died suddenly in his sleep at the team hotel last week. We're putting pressure on our rivals and we keep moving forwards.
Napoli needed three points to move top after Juventus defeated Udinese earlier in the day.
Napoli carved out a chance of their own after 67 minutes when Lorenzo Insigne broke through on goal, but with only Samir Handanovic to beat, he lobbed the ball over the crossbar.
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Fiorentina paid tribute to their late captain Davide Astori before and during the 1-0 win over Benevento at Stadio Artemio Franchi.
Duvan Zapata scored Sampdoria's only goal in the match.
Vitor Hugo headed the only goal in the 25th minute and celebrated by hugging coach Stefano Pioli before raising a shirt with a picture of Astori on it to the crowd.
Ciro Immobile grabbed Lazio a 2-2 draw at Cagliari with a stunning equaliser in the fifth minute of injury time.
Andre Silva struck in the fourth minute of second-half stoppage time to seal a 1-0 win over AC Milan on Sunday evening.
Napoli have missed out on the chance to return to the top of the Serie A table as they were held to a goalless draw at Inter Milan on Sunday night.
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